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Is acrylonitrile more likely to undergo anionic or cationic polymerization? Explain your answer.

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Acrylonitrile is more likely t...

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Give the purpose of the amine in the formation of the epoxy resin.


A) a softener
B) hardener
C) a monomer in the reaction
D) to dehydrate the monomer
E) to chill the polymer

F) B) and C)
G) C) and D)

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Draw the structure of the polymer that results when methyl α-cyanoacrylate undergoes polymerization.By what name is this polymer commonly known?

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This polym...

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Chain-growth polymerization proceeds by which of the following mechanisms?


A) radical polymerization
B) cationic polymerization
C) anionic polymerization
D) A and B
E) A,B,and C

F) A) and C)
G) C) and D)

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In a recycling symbol,the ________ the number in the middle of the symbol,the more easily the compound can be recycled.

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Which of the following statements best describes what alpha olefins are?


A) polysubstituted ethylenes
B) monosubstituted ethylenes
C) disubstituted ethylenes
D) ethylenes
E) isoprenes

F) A) and D)
G) A) and C)

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What monomers formed the following polymer? What monomers formed the following polymer?   A) I B) II C) III D) IV E) V


A) I
B) II
C) III
D) IV
E) V

F) D) and E)
G) A) and D)

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Name the monomer used in the production of neoprene.

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2-chloro-1...

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Which of the following species can best serve as an initiator for anionic polymerization?


A) CH3CH2CH2CH2Li
B) BF3
C) HOOH
D) CH3CH2CH2CH2OH
E) CH3CH2CH2CH2OCH2CH2CH2CH3

F) B) and D)
G) A) and B)

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Draw the structure of the polymer produced in the following reaction. Draw the structure of the polymer produced in the following reaction.

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Vulcanization involves crosslinking of polymer chains through


A) disulfide bonds
B) amide bonds
C) ester bonds
D) double bonds
E) manual twisting

F) A) and B)
G) A) and E)

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Which of the following is the chain-initiating step in the cationic polymerization of propene? Which of the following is the chain-initiating step in the cationic polymerization of propene?   A) I B) II C) III D) IV E) V


A) I
B) II
C) III
D) IV
E) V

F) B) and E)
G) C) and D)

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Which of the following polymers is arranged in an isotactic configuration? Which of the following polymers is arranged in an isotactic configuration?   A) I B) II C) III D) IV E) V


A) I
B) II
C) III
D) IV
E) V

F) B) and D)
G) A) and D)

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Identify the monomer(s) that undergo cationic polymerization.You may choose more than one answer.


A) styrene
B) methyl methacrylate
C) vinyl chloride
D) methyl vinyl ether
E) acrylamide

F) A) and E)
G) C) and E)

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Show the mechanism for the formation of a segment of polystyrene containing two molecules of styrene and initiated by hydrogen peroxide.

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Which of the following is more likely to form non-terminated polymeric chains called living polymers?


A) cationic polymerization
B) free radical polymerization
C) anionic polymerization
D) A and B
E) A and C

F) C) and E)
G) A) and E)

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What are elastomers?


A) elastic organic molecules that are added to polymers to make them harder
B) plastics that stretch and then revert to their original shape
C) polymers that are soft and sticky
D) plastics that are hard and brittle
E) elastic molecules that are added to polymers to make them stretch more

F) C) and E)
G) B) and E)

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Which of the following species can best serve as a radical initiator for radical polymerization?


A) ROH
B) ROR
C) ROOR
D) RCOOR
E) RCOOH

F) B) and D)
G) None of the above

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Chain-growth polymerization exhibits a marked preference for


A) tail-to-tail addition
B) head-to-head addition
C) head-to-tail addition
D) head-to-middle addition
E) middle-to-tail addition

F) D) and E)
G) C) and E)

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The choice of mechanism in chain-growth polymerization depends on which of the following?


A) structure of the monomer and initiator used
B) structure of the polymer and initiator used
C) temperature and pressure of the reaction
D) A and B
E) A,B,and C

F) B) and D)
G) C) and D)

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